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Now you are in the subtree of Energetic stability of quasicrystals project. 

Third order GL term

Here we derive the form of the 3rd order GL term due to the interaction between ions mediated by itinerant electrons.

ΔΩ(3)=v3q0ρq1ρq2ρq33βωn,kG1(ωn)G2(ωn)G3(ωn),

where ϵ1=ϵk, ϵ2=ϵkq1, and ϵ3=ϵkq1q2, and q1+q2+q3=0. By contour integration,

ΔΩ(3)=v3q0ρq1ρq2ρq33knF(ϵ1)(ϵ1ϵ2)(ϵ1ϵ3)+nF(ϵ2)(ϵ2ϵ1)(ϵ2ϵ3)+nF(ϵ3)(ϵ3ϵ1)(ϵ3ϵ2)λ(q0)ρq1ρq2ρq3.

The last equality follows from the assumption that densities condense only with a preferred wavevector magnitude, |q1,2,3|=q0, and hence qi form an equilateral triangle. Naturally, one expects that λ(q0) is singular when q0=2kFcos(π/6)=3kF, i.e. when the triangle is inscribed into the Fermi sphere/circle.