Third order GL term
Here we derive the form of the 3rd order GL term due to the interaction between ions mediated by itinerant electrons.
ΔΩ(3)=−v3q0ρq1ρq2ρq33β∑ωn,kG1(ωn)G2(ωn)G3(ωn),
where ϵ1=ϵk, ϵ2=ϵk−q1, and ϵ3=ϵk−q1−q2, and q1+q2+q3=0. By contour integration,
ΔΩ(3)=−v3q0ρq1ρq2ρq33∑knF(ϵ1)(ϵ1−ϵ2)(ϵ1−ϵ3)+nF(ϵ2)(ϵ2−ϵ1)(ϵ2−ϵ3)+nF(ϵ3)(ϵ3−ϵ1)(ϵ3−ϵ2)≡λ(q0)ρq1ρq2ρq3.
The last equality follows from the assumption that densities condense only with a preferred wavevector magnitude, |q1,2,3|=q0, and hence qi form an equilateral triangle. Naturally, one expects that λ(q0) is singular when q0=2kFcos(π/6)=√3kF, i.e. when the triangle is inscribed into the Fermi sphere/circle.